Contributions of CH4-amine interactions by primary, secondary, and tertiary amines on CO2/CH4 separation efficiency
نویسندگان
چکیده
In designing amine-incorporated adsorbents for CO2/CH4 separation, it is essential to understand the individual effects amine moieties have on separation of mixtures. this work, primary, secondary, and tertiary amines are moderately grafted SBA-15 examine factors affecting adsorption CO2 CH4. Materials were characterised by thermogravimetric elemental analysis, their performance was measured volumetric gravimetric gas adsorption. An density 1.6–1.7 mmol/g in secondary showed an equivalent CH4 uptake <0.04 at 25 °C, while primary adsorbed 0.05 mmol/g, indicating stronger interaction forces with terms selectivity, 1.3–1.4 had similar values, unaffected type. Adsorption results cross analysed DFT simulations indicate binding energies both moieties, concluding facilitated access molecules factor dictating degree At ? 1.7 amines, increase temperature from 40 °C a partial pressure kPa decrease selectivity only amines. Secondary thus more selective these conditions. Furthermore, isothermal adsorption–desorption conditions, equal working capacity Both qualities support moderate densities as candidates adsorbent development separations.
منابع مشابه
Equilibrium and Transport Properties of Primary, Secondary and Tertiary Amines by Molecular Simulation
Equilibrium and Transport Properties of Primary, Secondary and Tertiary Amines by Molecular Simulation — Using molecular simulation techniques such as Monte-Carlo (MC) and molecular dynamics (MD), we present several simulation results of thermodynamic and transport properties for primary, secondary and tertiary amines. These calculations are based on a recently proposed force field for amines t...
متن کاملEfficient metal-free hydrosilylation of tertiary, secondary and primary amides to amines.
Hydrosilylation of secondary and tertiary amides to amines is described using catalytic amounts of B(C6F5)3. The organic catalyst enables the reduction of amides with cost-efficient, non-toxic and air stable PMHS and TMDS hydrosilanes. The methodology was successfully extended to the more challenging reduction of primary amides.
متن کاملThe Comparision of Interactions Parent–Child and the Behavioral Problems Between Primary and Secondary enuresis
Background and Aim: The results of pervious researches in comparision psychological problems among primary and secondary enuresis has been inconstant. The aim of the present study was to compare the interactions between parent–child and the behavioral problems between these two subtypes. Methods: The present research design was of comparative type and its statistical population consisted of th...
متن کاملGeneral preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
متن کامل
Optimization of normal-phase chromatographic separation of compounds with primary, secondary and tertiary amino groups.
The retention behavior of primary, secondary and tertiary amines was studied using normal-phase-HPLC on silica, diol, and cyano stationary phases. Several classes of amines, including benzylamines, anilines, ephedrines, tryptamines, and azatryptamines were chromatographed using mixtures of hexane and ethoxynonafluorobutane with methylene chloride and methanol. Peak tailing, diminished selectivi...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Engineering Journal
سال: 2023
ISSN: ['1873-3212', '1385-8947']
DOI: https://doi.org/10.1016/j.cej.2023.142117